Lübken, D.; Saxarra, M.; Kalesse, M.: Tris(acetylacetonato) Iron(III): Recent Developments and Synthetic Applications. In: Synthesis (Germany) 51 (2019), Nr. 1, S. 161-177. DOI: https://doi.org/10.1055/s-0037-1610393
Abstract: | |
Tris(acetylacetonato) iron(III) [Fe(acac) 3 ] is an indispensable reagent in synthetic chemistry. Its applications range from hydrogen atom transfer to cross-coupling reactions and to use as a Lewis acid. Consequently, the exceptional utility of Fe(acac) 3 has been demonstrated in several total syntheses. This short review summarizes the applications of Fe(acac) 3 in methodology and catalysis and highlights its use for the synthesis of medicinally relevant structures and in natural product syntheses. 1 Introduction 2 Hydrogen Atom Transfer (HAT) 3 Oxidations and Radical Transformations 4 Synthesis and Use of Alkynes and Allenes 5 Cross-Couplings and Cycloisomerizations 6 Borylations 7 Miscellaneous Reactions 8 Conclusions. © 2018 Georg Thieme Verlag. All rights reserved. | |
License of this version: | CC BY-NC-ND 4.0 Unported |
Document Type: | Article |
Publishing status: | publishedVersion |
Issue Date: | 2019 |
Appears in Collections: | Naturwissenschaftliche Fakultät |
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Thailand | 21 | 8.43% |
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