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Lübken, D.; Saxarra, M.; Kalesse, M.: Tris(acetylacetonato) Iron(III): Recent Developments and Synthetic Applications. In: Synthesis (Germany) 51 (2019), Nr. 1, S. 161-177. DOI: https://doi.org/10.1055/s-0037-1610393
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Sum total of downloads: 249
| Abstract: | |
Tris(acetylacetonato) iron(III) [Fe(acac) 3 ] is an indispensable reagent in synthetic chemistry. Its applications range from hydrogen atom transfer to cross-coupling reactions and to use as a Lewis acid. Consequently, the exceptional utility of Fe(acac) 3 has been demonstrated in several total syntheses. This short review summarizes the applications of Fe(acac) 3 in methodology and catalysis and highlights its use for the synthesis of medicinally relevant structures and in natural product syntheses. 1 Introduction 2 Hydrogen Atom Transfer (HAT) 3 Oxidations and Radical Transformations 4 Synthesis and Use of Alkynes and Allenes 5 Cross-Couplings and Cycloisomerizations 6 Borylations 7 Miscellaneous Reactions 8 Conclusions. © 2018 Georg Thieme Verlag. All rights reserved. | |
| License of this version: | CC BY-NC-ND 4.0 Unported |
| Document Type: | Article |
| Publishing status: | publishedVersion |
| Issue Date: | 2019 |
| Appears in Collections: | Naturwissenschaftliche Fakultät |
distribution of downloads over the selected time period:
downloads by country:
| pos. | country | downloads | ||
|---|---|---|---|---|
| total | perc. | |||
| 1 |  |
Germany | 112 | 44.98% |
| 2 |  |
Thailand | 21 | 8.43% |
| 3 |  |
United States | 20 | 8.03% |
| 4 |  |
India | 11 | 4.42% |
| 5 |  |
Switzerland | 11 | 4.42% |
| 6 |  |
Iraq | 9 | 3.61% |
| 7 |  |
China | 9 | 3.61% |
| 8 |  |
United Kingdom | 6 | 2.41% |
| 9 |  |
Indonesia | 5 | 2.01% |
| 10 |  |
Canada | 5 | 2.01% |
| other countries | 40 | 16.06% | ||
Further download figures and rankings:
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