dc.identifier.uri |
http://dx.doi.org/10.15488/797 |
|
dc.identifier.uri |
http://www.repo.uni-hannover.de/handle/123456789/821 |
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dc.contributor.author |
Qiao, Zhiwei
|
|
dc.contributor.author |
Wang, Nanyi
|
|
dc.contributor.author |
Jiang, Jianwen
|
|
dc.contributor.author |
Zhou, Jian
|
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dc.date.accessioned |
2016-12-06T07:33:01Z |
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dc.date.available |
2016-12-06T07:33:01Z |
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dc.date.issued |
2016 |
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dc.identifier.citation |
Qiao, Zhiwei; Wang, Nanyi; Jiang, Jianwen; Zhou, Jian: Design of amine-functionalized metal-organic frameworks for CO2 separation: the more amine, the better? In: Chemical communications 52 (2016), Nr. 5, S. 974-977. DOI: http://dx.doi.org/10.1039/C5CC07171B |
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dc.description.abstract |
A total of 41,825 metal-organic frameworks (MOFs) were computationally screened toward the design of amine-functionalized MOFs for CO2 separation. Both the optimal species and number of amine functional groups were examined for eight MOFs with good performance in terms of CO2 uptake and selectivity. It was revealed that more amine functional groups grafted on the MOFs do not lead to a better CO2 separation capability, and the concept of saturation degree of functional groups was proposed. The ethylene-diamine-functionalized MOF-74 membrane was predicted to possess high CO2 permeation separation capability, which was confirmed by the parallel experimental test of gas permeation. |
eng |
dc.description.sponsorship |
National Key Basic Research Program of China/2013CB73350 |
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dc.description.sponsorship |
National Natural Science Foundation of China/21376089 |
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dc.description.sponsorship |
National Natural Science Foundation of China/91334202 |
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dc.description.sponsorship |
China Postdoctoral Science Foundation/2014M560663 |
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dc.description.sponsorship |
Guangdong Science Foundation/2014A03031200 |
|
dc.description.sponsorship |
Guangdong Science Foundation/2014A03031026 |
|
dc.description.sponsorship |
Fundamental Research Funds for the Central Universities/SCUT-2014ZB0012 |
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dc.description.sponsorship |
Fundamental Research Funds for the Central Universities/2015ZP03 |
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dc.description.sponsorship |
State Key Lab of Pulp and Paper Engineering Program/201444 |
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dc.description.sponsorship |
National University of Singapore for CENGas |
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dc.language.iso |
eng |
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dc.publisher |
Cambridge : Royal Society of Chemistry |
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dc.relation.ispartofseries |
Chemical communications 52 (2016), Nr. 5 |
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dc.rights |
Es gilt deutsches Urheberrecht. Das Dokument darf zum eigenen Gebrauch kostenfrei genutzt, aber nicht im Internet bereitgestellt oder an Außenstehende weitergegeben werden. Dieser Beitrag ist aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich. |
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dc.subject |
metal-organic frameworks |
eng |
dc.subject |
MOFs |
eng |
dc.subject |
CO2 separation |
eng |
dc.subject |
MOF-74 |
eng |
dc.subject.ddc |
540 | Chemie
|
ger |
dc.title |
Design of amine-functionalized metal-organic frameworks for CO2 separation: the more amine, the better? |
eng |
dc.type |
Article |
|
dc.type |
Text |
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dc.relation.essn |
1364-548X |
|
dc.relation.issn |
1359-7345 |
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dc.relation.doi |
http://dx.doi.org/10.1039/C5CC07171B |
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dc.bibliographicCitation.issue |
5 |
|
dc.bibliographicCitation.volume |
52 |
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dc.bibliographicCitation.firstPage |
974 |
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dc.bibliographicCitation.lastPage |
977 |
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dc.description.version |
publishedVersion |
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tib.accessRights |
frei zug�nglich |
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