dc.identifier.uri | http://dx.doi.org/10.15488/2481 | |
dc.identifier.uri | http://www.repo.uni-hannover.de/handle/123456789/2507 | |
dc.contributor.author | Schleid, Thomas | |
dc.contributor.author | Meyer, Gerd | |
dc.date.accessioned | 2017-11-24T12:08:40Z | |
dc.date.available | 2017-11-24T12:08:40Z | |
dc.date.issued | 1989 | |
dc.identifier.citation | Schleid, T.; Meyer, G.: Synthese und Kristallstruktur von Europium(III)-diacetatotriaquo-chlorid, [Eu(CH3COO)2(H2O)3]Cl. In: Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 44 (1989), Nr. 9, S. 1007-1010. DOI: https://doi.org/10.1515/znb-1989-0903 | |
dc.description.abstract | Colourless single crystals of [Eu(CH3COO)2(H2O)3]Cl are obtained at about 5°C from a solution of EuCl3 · 6 H2O in a mixture of acetone, tetrahydrofurane and acetanhydride (1:1:2) to which a small amount of water had been added. [Eu(CH3COO)2(H2O)3]Cl crystallizes in the monoclinic system, space group P21/n (No. 14), a = 786.19(5), b = 791.86(5), c = 1768.81(13) pm; β = 98.235(6)°, R = 0.025, Rw = 0.021, Z = 4. Eu3+ is in nine-coordinate surrounding of O2-, three of which belong to water molecules and six to acetate anions (two bidentate and two monodentate). Cationic chains of the composition [Eu(CH3COO)2(H2O)3]+ are formed through further connection via acetate-oxygen atoms. These chains are stacked hexagonally parallel [100] and held together by “lonesome” Cl- anions. The chloride ions are surrounded by 4+1 aquo ligands. | eng |
dc.language.iso | ger | |
dc.publisher | Berlin : De Gruyter | |
dc.relation.ispartofseries | Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 44 (1989), Nr. 9 | |
dc.rights | CC BY-NC-ND 3.0 Unported | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ | |
dc.subject | Crystal Structure | eng |
dc.subject | Rare Earth Acetate Chloride | eng |
dc.subject | Synthesis | eng |
dc.subject.ddc | 540 | Chemie | ger |
dc.title | Synthese und Kristallstruktur von Europium(III)-diacetatotriaquo-chlorid, [Eu(CH3COO)2(H2O)3]Cl | ger |
dc.type | Article | |
dc.type | Text | |
dc.relation.essn | 1865-7117 | |
dc.relation.issn | 0932-0776 | |
dc.relation.doi | https://doi.org/10.1515/znb-1989-0903 | |
dc.bibliographicCitation.issue | 9 | |
dc.bibliographicCitation.volume | 44 | |
dc.bibliographicCitation.firstPage | 1007 | |
dc.bibliographicCitation.lastPage | 1010 | |
dc.description.version | publishedVersion | |
tib.accessRights | frei zug�nglich |
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