dc.identifier.uri | http://dx.doi.org/10.15488/2414 | |
dc.identifier.uri | http://www.repo.uni-hannover.de/handle/123456789/2440 | |
dc.contributor.author | Lossin, Adalbert | |
dc.contributor.author | Meyer, Gerd | |
dc.date.accessioned | 2017-11-24T10:07:37Z | |
dc.date.available | 2017-11-24T10:07:37Z | |
dc.date.issued | 1992 | |
dc.identifier.citation | Lossin, A.; Meyer, G.: Dimere und Ketten in Praseodym(III)acetat-sesquihydrat, Pr(CH3COO)3l, 5H20. In: Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 47 (1992), Nr. 11, S. 1602-1608. DOI: https://doi.org/10.1515/znb-1992-1114 | |
dc.description.abstract | Pr(CH3COO)3· 1.5 H2O crystallizes with the triclinic system, P̄1̄ (no. 2), Z = 4, a = 844.2(4), b = 1009.8(5), c = 1340.1(7) pm, α = 87.10(5), β = 76.25(6), y = 75.65(2)°, Vm = 161.9(1) cm3/mol, R = 0.049, Rw = 0.035. The crystal structure contains centrosymmetric dimers {[Pr(CH3COO)4(H2O)]-}2 and one-dimensional chains ∞1[Pr(CH3COO)2(H2O)]+ along the [100] direction. Both units are built up by bridging acetate groups. The chains are linked by the dimers to layers parallel (101) sharing oxygen atoms. Crystal water molecules between these planes form hydrogen bonds to neighbouring layers. | eng |
dc.language.iso | ger | |
dc.publisher | Berlin : De Gruyter | |
dc.relation.ispartofseries | Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 47 (1992), Nr. 11 | |
dc.rights | CC BY-NC-ND 3.0 Unported | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ | |
dc.subject | Crystal Structure | eng |
dc.subject | Praseodymium Acetate | eng |
dc.subject | Sesquihydrate | eng |
dc.subject | Synthesis | eng |
dc.subject | Thermal Behaviour | eng |
dc.subject.ddc | 540 | Chemie | ger |
dc.title | Dimere und Ketten in Praseodym(III)acetat-sesquihydrat, Pr(CH3COO)3l, 5H20 | ger |
dc.type | Article | |
dc.type | Text | |
dc.relation.essn | 1865-7117 | |
dc.relation.issn | 0932-0776 | |
dc.relation.doi | https://doi.org/10.1515/znb-1992-1114 | |
dc.bibliographicCitation.issue | 11 | |
dc.bibliographicCitation.volume | 47 | |
dc.bibliographicCitation.firstPage | 1602 | |
dc.bibliographicCitation.lastPage | 1608 | |
dc.description.version | publishedVersion | |
tib.accessRights | frei zug�nglich |
Die folgenden Lizenzbestimmungen sind mit dieser Ressource verbunden: