dc.identifier.uri | http://dx.doi.org/10.15488/2392 | |
dc.identifier.uri | http://www.repo.uni-hannover.de/handle/123456789/2418 | |
dc.contributor.author | Holzbach, Wolfgang | |
dc.contributor.author | Wieghardt, Karl | |
dc.contributor.author | Weiss, Johannes | |
dc.date.accessioned | 2017-11-24T08:14:41Z | |
dc.date.available | 2017-11-24T08:14:41Z | |
dc.date.issued | 1981 | |
dc.identifier.citation | Holzbach, W.; Wieghardt, K.; Weiss, J.: Darstellung und Kristallstruktur von Bis-(N-Methymydroxylamido(1-)-O.N)(N-methyl-N-oxo-dithiocarbamato-O.S)-oxo-molybdän(VI). In: Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 36 (1981), Nr. 3, S. 289-292. DOI: https://doi.org/10.1515/znb-1981-0302 | |
dc.description.abstract | The reaction of [MoO2((CH3)HN-O)2] and N-methylhydroxylammoniumchloride in an aqueous suspension with CS2 yields red crystals of the analytical composition MOC4H14N3O4S2. The crystal structure has been determined by single crystal X-ray diffraction analysis. The compound crystallizes in the monoclinic space group P21/c, with cell constants a= 1333.2(3), b = 814.2(2), c = 2179.8(6) pm, β = 105.42(2)°, and Z = 8. The final R-value is 4.5% for 2965 unique reflexions. The structure consists of two crystallographically independent neutral complexes of molybdenum(VI). The geometry about the molybdenum is a distorted pentagonal bipyramid containing a terminal oxygen atom, two N-methylhydroxylamido(1-) ligands coordinated via the O-and N-atoms and an N-methyl-N-oxo-dithiocarbamato(2-) ligand forming a planar five membered ring with the molybdenum(VI) center (O,S-coordination). | eng |
dc.language.iso | ger | |
dc.publisher | Berlin : De Gruyter | |
dc.relation.ispartofseries | Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 36 (1981), Nr. 3 | |
dc.rights | CC BY-NC-ND 3.0 Unported | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ | |
dc.subject | Bis(N-methylhydroxylamido(1-)-O, N)(N-methyl-N-oxo-dithiocarbamato-O,S)-oxo-molybdenum(VI) | eng |
dc.subject | Crystal Structure | eng |
dc.subject | Synthesis | eng |
dc.subject.ddc | 540 | Chemie | ger |
dc.title | Darstellung und Kristallstruktur von Bis-(N-Methymydroxylamido(1-)-O.N)(N-methyl-N-oxo-dithiocarbamato-O.S)-oxo-molybdän(VI) | ger |
dc.type | Article | |
dc.type | Text | |
dc.relation.essn | 1865-7117 | |
dc.relation.issn | 0932-0776 | |
dc.relation.doi | https://doi.org/10.1515/znb-1981-0302 | |
dc.bibliographicCitation.issue | 3 | |
dc.bibliographicCitation.volume | 36 | |
dc.bibliographicCitation.firstPage | 289 | |
dc.bibliographicCitation.lastPage | 292 | |
dc.description.version | publishedVersion | |
tib.accessRights | frei zug�nglich |
Die folgenden Lizenzbestimmungen sind mit dieser Ressource verbunden: