dc.identifier.uri | http://dx.doi.org/10.15488/2390 | |
dc.identifier.uri | http://www.repo.uni-hannover.de/handle/123456789/2416 | |
dc.contributor.author | Lossin, Adalbert | |
dc.contributor.author | Meyer, Gerd | |
dc.date.accessioned | 2017-11-24T08:14:41Z | |
dc.date.available | 2017-11-24T08:14:41Z | |
dc.date.issued | 1993 | |
dc.identifier.citation | Lossin, A.; Meyer, G.: CsPr2(CH3COO)7, ein caesiumarmes wasserfreies ternäres Caesium-Praseodym-Acetat. In: Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 48 (1993), Nr. 7, S. 886-892. DOI: https://doi.org/10.1515/znb-1993-0705 | |
dc.description.abstract | Single crystals of CsPr2(CH3COO)7 were obtained from an acetic acid solution of Pr(CH3COO)3 • H2O and Cs2CO3 in a molar ratio of 4:1 at 120°C. It crystallizes in the triclinic system, PĪ (no. 2), Z = 2, a = 1028.1(5), b = 1034.6(5), c = 1199.4(6) pm, α = 84.82(2), β = 67.07(3), γ = 76.01(2)°, Vm = 343.3(3) cm3/mol, R = 0.031, Rw = 0.027. The crystal structure contains infinite chains, 1∞[Pr2(CH3COO)6], running along the [110] direction. The chains are built up by bridging acetate ions coordinated to two crystallographically different Pr3+ ions which are both surrounded by 9 oxygen ligands. These chains are linked by “intercalated” Cs(CH3COO) to layers parallel (100). Cs+ has contacts to oxygen atoms of neighbouring layers, such that a three-dimensional network is formed. | eng |
dc.language.iso | ger | |
dc.publisher | Berlin : De Gruyter | |
dc.relation.ispartofseries | Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 48 (1993), Nr. 7 | |
dc.rights | CC BY-NC-ND 3.0 Unported | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ | |
dc.subject | Cesium Praseodym Acetate | eng |
dc.subject | Crystal Structure | eng |
dc.subject | Synthesis | eng |
dc.subject.ddc | 540 | Chemie | ger |
dc.title | CsPr2(CH3COO)7, ein caesiumarmes wasserfreies ternäres Caesium-Praseodym-Acetat | ger |
dc.type | Article | |
dc.type | Text | |
dc.relation.essn | 1865-7117 | |
dc.relation.issn | 0932-0776 | |
dc.relation.doi | https://doi.org/10.1515/znb-1993-0705 | |
dc.bibliographicCitation.issue | 7 | |
dc.bibliographicCitation.volume | 48 | |
dc.bibliographicCitation.firstPage | 886 | |
dc.bibliographicCitation.lastPage | 892 | |
dc.description.version | publishedVersion | |
tib.accessRights | frei zug�nglich |
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