dc.identifier.uri |
http://dx.doi.org/10.15488/16591 |
|
dc.identifier.uri |
https://www.repo.uni-hannover.de/handle/123456789/16718 |
|
dc.contributor.author |
Brehme, Jules
|
|
dc.contributor.author |
Kilic, Maximilian Seydi
|
|
dc.contributor.author |
Pawlak, Justus
|
|
dc.contributor.author |
Renz, Franz
|
|
dc.contributor.author |
Sindelar, Ralf Franz
|
|
dc.date.accessioned |
2024-03-15T09:40:21Z |
|
dc.date.available |
2024-03-15T09:40:21Z |
|
dc.date.issued |
2024 |
|
dc.identifier.citation |
Brehme, J.; Kilic, M.S.; Pawlak, J.; Renz, F.; Sindelar, R.F.: Soluble molecular switches in electrospun nanofibers. In: Interactions 245 (2024), Nr. 1, 10. DOI: https://doi.org/10.1007/s10751-024-01842-z |
|
dc.description.abstract |
Compounds that exhibit the spin crossover effect are known to show a change of spin states through external stimuli. This reversible switching of spin states is accompanied by a change of the properties of the compound. Complexes, like iron (II)-triazole complexes, that exhibit this behavior at ambient temperature are often discussed for potential applications. In previous studies we synthesized iron (II)-triazole complexes and implemented them into electrospun nanofibers. We used Mössbauer spectroscopy in first studies to prove a successful implementation with maintaining spin crossover properties. Further studies from us showed that it is possible to use different electrospinning methods to either do a implementation or a deposition of the synthesized solid SCO material into or onto the polymer nanofibers. We now used a solvent in which both, the used iron (II)-triazole complex [Fe(atrz)3](2 ns)2 and three different polymers (Polyacrylonitrile, Polymethylmethacrylate and Polyvinylpyrrolidone), are soluble. This shall lead to a higher homogeneous distribution of the complex along the nanofibers. Mössbauer spectroscopy and other measurements are therefore in use to show a successful implementation without any significant changes to the complex. |
eng |
dc.language.iso |
eng |
|
dc.publisher |
[Cham] : Springer Nature Switzerland |
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dc.relation.ispartofseries |
Interactions 245 (2024), Nr. 1 |
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dc.rights |
CC BY 4.0 Unported |
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dc.rights.uri |
https://creativecommons.org/licenses/by/4.0 |
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dc.subject |
Electrospinning |
eng |
dc.subject |
Molecular switches |
eng |
dc.subject |
Mössbauer |
eng |
dc.subject |
SCO |
eng |
dc.subject |
Triazole |
eng |
dc.subject.ddc |
530 | Physik
|
|
dc.title |
Soluble molecular switches in electrospun nanofibers |
eng |
dc.type |
Article |
|
dc.type |
Text |
|
dc.relation.essn |
3005-0731 |
|
dc.relation.doi |
https://doi.org/10.1007/s10751-024-01842-z |
|
dc.bibliographicCitation.issue |
1 |
|
dc.bibliographicCitation.volume |
245 |
|
dc.bibliographicCitation.firstPage |
10 |
|
dc.description.version |
publishedVersion |
|
tib.accessRights |
frei zug�nglich |
|