Minority carrier lifetime in silicon photovoltaics: The effect of oxygen precipitation

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Murphy, J.D.; McGuire, R.E.; Bothe, K.; Voronkov, V.V.; Falster, R.J.: Minority carrier lifetime in silicon photovoltaics: The effect of oxygen precipitation. In: Solar Energy Materials and Solar Cells 120 (2014), S. 402-411. DOI: https://doi.org/10.1016/j.solmat.2013.06.018

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Sum total of downloads: 190




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Abstract: 
Single-crystal Czochralski silicon used for photovoltaics is typically supersaturated with interstitial oxygen at temperatures just below the melting point. Oxide precipitates therefore can form during ingot cooling and cell processing, and nucleation sites are typically vacancy-rich regions. Oxygen precipitation gives rise to recombination centres, which can reduce cell efficiencies by as much as 4% (absolute). We have studied the recombination behaviour in p-type and n-type monocrystalline silicon with a range of doping levels intentionally processed to contain oxide precipitates with a range of densities, sizes and morphologies. We analyse injection-dependent minority carrier lifetime measurements to give a full parameterisation of the recombination activity in terms of Shockley-Read-Hall statistics. We intentionally contaminate specimens with iron, and show recombination activity arises from iron segregated to oxide precipitates and surrounding defects. We find that phosphorus diffusion gettering reduces the recombination activity of the precipitates to some extent. We also find that bulk iron is preferentially gettered to the phosphorus diffused layer rather than to oxide precipitates. © 2013 The Authors.
License of this version: CC BY 3.0 Unported
Document Type: Article
Publishing status: publishedVersion
Issue Date: 2014
Appears in Collections:An-Institute

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pos. country downloads
total perc.
1 image of flag of Germany Germany 108 56.84%
2 image of flag of United States United States 26 13.68%
3 image of flag of China China 15 7.89%
4 image of flag of France France 7 3.68%
5 image of flag of Taiwan Taiwan 3 1.58%
6 image of flag of Russian Federation Russian Federation 3 1.58%
7 image of flag of Latvia Latvia 3 1.58%
8 image of flag of Japan Japan 3 1.58%
9 image of flag of Israel Israel 2 1.05%
10 image of flag of Czech Republic Czech Republic 2 1.05%
    other countries 18 9.47%

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