Effect of Cu2O Substrate on Photoinduced Hydrophilicity of TiO2 and ZnO Nanocoatings

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Maevskaya, M.V.; Rudakova, A.V.; Emeline, A.V.; Bahnemann, D.W.: Effect of Cu2O Substrate on Photoinduced Hydrophilicity of TiO2 and ZnO Nanocoatings. In: Nanomaterials 11 (2021), Nr. 6, 1526. DOI: https://doi.org/10.3390/nano11061526

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The effect of a Cu2 O substrate on the photoinduced alteration of the hydrophilicity of TiO2 and ZnO surfaces was studied. It was demonstrated that the formation of heterostructures Cu2 O/TiO2 and Cu2 O/ZnO strongly changed the direction of the photoinduced alteration of surface hydrophilicity: while both TiO2 and ZnO demonstrate surface transition to superhydrophilic state under UV irradiation and no significant alteration of the surface hydrophilicity under visible light irradiation, the formation of Cu2 O/TiO2 and Cu2 O/ZnO heterostructures resulted in photoinduced decay of the surface hydrophilicity caused by both UV and visible light irradiation. All observed photoinduced changes of the surface hydrophilicity were compared and analyzed in terms of pho-toinduced alteration of the surface free energy and its polar and dispersive components. Alteration of the photoinduced hydrophilic behavior of TiO2 and ZnO surfaces caused by formation of the corresponding heterostructures with Cu2 O are explained within the mechanism of electron transfer and increasing of the electron concentration on the TiO2 and ZnO surfaces.
License of this version: CC BY 4.0 Unported
Document Type: Article
Publishing status: publishedVersion
Issue Date: 2021
Appears in Collections:Naturwissenschaftliche Fakultät

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pos. country downloads
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1 image of flag of United States United States 8 32.00%
2 image of flag of Germany Germany 7 28.00%
3 image of flag of United Kingdom United Kingdom 2 8.00%
4 image of flag of No geo information available No geo information available 1 4.00%
5 image of flag of Ukraine Ukraine 1 4.00%
6 image of flag of Russian Federation Russian Federation 1 4.00%
7 image of flag of Netherlands Netherlands 1 4.00%
8 image of flag of Mexico Mexico 1 4.00%
9 image of flag of Canada Canada 1 4.00%
10 image of flag of Australia Australia 1 4.00%
    other countries 1 4.00%

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