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Natke, D.; Preiss, A.; Klimke, S.; Shiga, T.; Boca, R. et al.: Structural, Magnetic, and Electrochemical Characterization of Iron(III) and Cobalt Complexes with Penta-N3O2-dentate Ligands. In: European Journal of Inorganic Chemistry 2021 (2021), Nr. 15, S. 1498-1504. DOI: https://doi.org/10.1002/ejic.202100081
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Sum total of downloads: 55
| Abstract: | |
Six new mononuclear [FeIII(LBr,Cl)X]-complexes (LBr,Cl is the dianionic penta-N3O2-dentate Schiff base ligand N,N′-bis(2’-hydroxy-3-bromo-5-chlorobenzylidene)-1,6-diamino-3-azahexane; X: Cl−, N3−, NCO−, NCS−, NCSe−, CN−) were synthesized and their structures, magnetic and electrochemical properties studied. Structure analysis and magnetic measurements showed that [FeIII(LBr,Cl)CN] is in the low spin state and the other five complexes are in high spin states. Furthermore, the trinuclear mixed valent cobalt complex {[CoIII(LH,H)CN]2[CoII(1-methylimidazole)3(H2O)]} was prepared and its magnetic behavior studied. © 2021 The Authors. European Journal of Inorganic Chemistry published by Wiley-VCH GmbH | |
| License of this version: | CC BY 4.0 Unported |
| Document Type: | Article |
| Publishing status: | publishedVersion |
| Issue Date: | 2021 |
| Appears in Collections: | Naturwissenschaftliche Fakultät |
distribution of downloads over the selected time period:
downloads by country:
| pos. | country | downloads | ||
|---|---|---|---|---|
| total | perc. | |||
| 1 |  |
Germany | 19 | 34.55% |
| 2 |  |
United States | 17 | 30.91% |
| 3 |  |
No geo information available | 7 | 12.73% |
| 4 |  |
China | 5 | 9.09% |
| 5 |  |
Taiwan | 1 | 1.82% |
| 6 |  |
Russian Federation | 1 | 1.82% |
| 7 |  |
Portugal | 1 | 1.82% |
| 8 |  |
Peru | 1 | 1.82% |
| 9 |  |
Japan | 1 | 1.82% |
| 10 |  |
India | 1 | 1.82% |
| other countries | 1 | 1.82% | ||
Further download figures and rankings:
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