Browsing by Subject "Thermodynamic data"

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AsS2Cl - An arsenic(V) compound? Formation, stability and structure of gaseous AsSCl and AsS2Cl - A combined experimental and theoretical study

Milke, E.; Köppe, R.; Binnewies, Michael (Cambridge : Royal Society of Chemistry, 2011)

By reaction of solid As4S4 with gaseous Cl2 at a temperature of 410 K gaseous AsSCl and AsS2Cl are formed. Unexpectedly in AsS2Cl the arsenic is not of formal oxidation state +V but +III: the molecular structure of AsS2Cl ...
The formation and stability of molybdenum-antimony and tungsten-antimony ternary oxides Sb 2MO 6, Sb 2M 2O 9, Sb 2Mo 3O 12 and Sb 4MO 9 in the gas phase (M = Mo, W). Quantum chemical and mass spectrometric studies

Berezovskaya, E.; Milke, E.; Binnewies, Michael (Cambridge : Royal Society of Chemistry, 2012)

The ternary oxides Sb 2MO 6, Sb 2M 2O 9, Sb 4MO 9 (M = Mo, W) and Sb 2Mo 3O 12 were detected in the gas phase by means of mass spectrometry (MS). These gaseous oxides are reported for the first time. Thermodynamic data was ...
Thorium nanochemistry: The solution structure of the Th(iv)-hydroxo pentamer

Walther, C.; Rothe, J.; Schimmelpfennig, B.; Fuss, M. (Cambridge : Royal Society of Chemistry, 2012)

Tetravalent thorium exhibits a strong tendency towards hydrolysis and subsequent polymerization. Polymeric species play a crucial role in understanding thorium solution chemistry, since their presence causes apparent ...

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